TY - JOUR U1 - Zeitschriftenartikel, wissenschaftlich - begutachtet (reviewed) A1 - AlSalem, Huda S. A1 - Al-Goul, Soha T. A1 - Ferrari, Alejandro García-Miranda A1 - Brownson, Dale A. C. A1 - Velarde, Luis A1 - Köhler, Sven P. K. T1 - Imaging the reactivity and width of graphene’s boundary region JF - Chemical Communications N2 - The reactivity of graphene at its boundary region has been imaged using non-linear spectroscopy to address the controversy whether the terraces of graphene or its edges are more reactive. Graphene was functionalised with phenyl groups, and we subsequently scanned our vibrational sum-frequency generation setup from the functionalised graphene terraces across the edges. A greater phenyl signal is clearly observed at the edges, showing evidence of increased reactivity in the boundary region. We estimate an upper limit of 1 mm for the width of the CVD graphene boundary region. KW - Graphen KW - Reaktivität KW - Nichtlineare Spektroskopie Y1 - 2020 UN - https://nbn-resolving.org/urn:nbn:de:bsz:960-opus4-22589 SN - 1364-548X SS - 1364-548X U6 - https://doi.org/10.25968/opus-2258 DO - https://doi.org/10.25968/opus-2258 VL - 56 IS - 67 SP - 9612 EP - 9615 ER -